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We report a unique strategy for the development of a H2O2‐dependent cytochrome P450BM3 system, which catalyzes the monooxygenation of non‐native substrates with the assistance of dual‐functional small molecules (DFSMs), such as N‐(ω‐imidazolyl fatty acyl)‐l‐amino acids. The acyl amino acid group of DFSM is responsible for bounding to enzyme as an anchoring group, while the imidazolyl group plays the...
Enzymkatalyse In ihrer Zuschrift auf S. 7754 berichten Z. Cong et al. über einen neuen Ansatz für die Umwandlung von P450‐Monooxygenasen in Peroxygenasen. Die Methode hat großes Potenzial für die organische Synthese.
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