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Dinitrogen coordination to iron centers underpins industrial and biological fixation in the Haber–Bosch process and by the FeM cofactors in the nitrogenase enzymes. The latter employ local high‐spin metal centers; however, iron–dinitrogen coordination chemistry remains dominated by low‐valent states, contrasting the enzyme systems. Here, we report a high‐spin mixed‐valent cis‐(μ‐1,2‐dinitrogen)diiron(I/II)...
Dinitrogen coordination to iron centers underpins industrial and biological fixation in the Haber–Bosch process and by the FeM cofactors in the nitrogenase enzymes. The latter employ local high‐spin metal centers; however, iron–dinitrogen coordination chemistry remains dominated by low‐valent states, contrasting the enzyme systems. Here, we report a high‐spin mixed‐valent cis‐(μ‐1,2‐dinitrogen)diiron(I/II)...
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