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Acrylic polymers, which can be applied as pressure-sensitive adhesives (PSA), based on 2-ethylhexyl acrylate, methyl acrylate, and acrylic acid were synthesized in ethyl acetate using azoperoxyester radical initiators. First, the investigated azoperoxyesters were synthesized and isolated. In a second stage, the thermally activated azo groups initiated the radical polymerization of the acrylate monomers...
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