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Polypropylene/polyhedral oligomeric silsesquioxane (PP/POSS) nanocomposites were prepared by the melt blending method. Positron Annihilation Lifetime Spectroscopy (PALS) was used to study the effects of the structure and of the amount of POSS on the free volumes in PP. The PALS parameters: o-Ps lifetime and its intensity, were compared to the crystallinity degree and to the mass flow rate (MFR) of...
Artykuł stanowi kontynuację przeglądu literatury dotyczącej koordynacyjnej polimeryzacji silseskwioksanów (POSS), zawierających zdolne do polimeryzacji wiązanie podwójne, oraz ich kopolimeryzacji głównie zolefinami, atakże ze styrenem. Zastosowanie katalizatorów metalocenowych aktywowanych metyloaluminoksanem (MAO) zapewnia efektywną (ko)polimeryzację silseskwioksanów zarówno zolefinami, jak istyrenem...
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