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Plate-like stoichiometric crystals of Ag-doped LiCu2O2 have been grown by slowly cooling Li2CO3·4(1 – x)CuO·4xAgNO3 (0 ≤ x ≤ 0.5) melts. X-ray single crystal diffraction has shown that the crystals are isostructural with LiCu2O2 and contain around 5 at % Ag (relative to the Cu atoms). The addition of silver to lithium cuprate crystals significantly increases their electrical conductivity but has little...
Temperature-dependent crystallographic and magnetic studies on stoichiometric single crystals of LiCu 2 O 2 are reported. The temperature dependence of the lattice parameters was extracted from X-ray powder diffractograms collected on crushed single crystals, from 12 K to 295 K. The magnetic properties are similar to earlier findings demonstrating antiferromagnetic ordering below 25 K...
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