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Infrared reflection absorption spectroscopy (IRRAS) was used to investigate carbon monoxide (CO) adsorption on Pt(100) surfaces deposited with Co layers with different thicknesses. Pt(100) surfaces cleaned in ultrahigh vacuum showed surface reconstruction, i.e., Pt(100)-hex: two absorption bands ascribable to adsorbed CO on the 1×1 surface and hex domains emerge at 2086 and 2074cm −1 , respectively,...
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