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Nanoparticles can be assembled into complex structures and architectures by using a variety of methods. In this review, we discuss recent progress of using polymer crystallization (particularly polymer single crystals, PSCs) to direct nanoparticle assembly. PSCs have been extensively studied since 1957. Mainly appearing as quasi‐two‐dimensional (2D) lamellae, PSCs are typically used as model systems...
Polymer single crystals (PSCs) mainly appearing as quasi‐two‐dimensional lamellae and are typically used as model systems to determine polymer crystalline structures. Recent research has demonstrated that they can also be used as nanoscale functional materials. In particular, nanoparticles can be directed to assemble into complex shapes by using in situ or ex situ polymer crystal growth. End‐functionalized...
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