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Three new Ru complexes with N‐P(OH)‐N donor ligands were synthesized and characterized. A ruthenium complex with a ligand with quinolinyl side arms exhibited monodentate coordination through the phosphorus atom with an intramolecular POH⋅⋅⋅N(quinolinyl) hydrogen bond but with no interaction between nitrogen donors and the ruthenium center. Two pentamethylcyclopentadienyl ruthenium complexes with a...
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