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The trapping of a phosphinidene (R‐P) in an NCN pincer is presented. Stabilized phosphinidene 1 was characterized by 31P{1H}, 1H, and 13C{1H} NMR spectroscopy, exhibiting an averaged C2v symmetry in solution between −60 and 60 °C. In the solid state, the phosphinidene is coordinated by one adjacent N atom featuring a formal P−N bond (1.757(2) Å) to give a five‐membered ring with some aromatic character,...
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