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Various linear and branched oligoglycidol macromonomers are prepared using anionic ring opening polymerization of the monomers ethoxyethyl glycidyl ether (EEGE) and glycidol. Starting with 4‐vinyl benzyl alcohol (VBA), allyl glycol or N‐(2‐hydroxyethyl) methacryl amide (HEMAm) oligoglycidol macromomonomers with three to six repeating units are obtained in good yields and characterized with NMR, SEC,...
Anionic polymerization of EEGE with alkali metal based initiators has been shown to yield polyglycidol with low polydispersity indices for molecular weights up to M n ≈30,000. Higher molecular weights have not been obtained due to the occurrence of a chain transfer reaction to the monomer. Chain transfer to the monomer leads to P(EEGE) with an alcohol end group and an allylic alcoholate, which...
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