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Artificial light‐driven splitting of water into hydrogen involves multiple links to emulate natural photosynthesis, including light absorption, electron or energy transfer, surface catalysis et al., in which, the mass transportation of sacrificial reagent and reactant is always ignored. Metal‐organic cage (MOC) of Pd6Ru8 (MOC‐16), assembling multiple photosensitive Ru and catalytic Pd concomitant...
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