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Complexes of diethylmalonate, a common building block in organic synthesis, with gold(I) and silver(I) have been investigated. Both metal cations coordinate between the two carbonyl-oxygen atoms of diethylmalonate. The gold(I) complex should also bear diethylmalonate in the enol-form in the gas phase, while the diketo form is preferred in the condensed phase. The IRMPD spectrum shows that the diketo...
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