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Using the luminescent properties of temperature‐sensitive paints (TSPs) to monitor temperature is a new type of temperature measurement technology. Herein, Na9[EuW10O36](EuW10) molecules were doped with non‐fluorescent rare earth metal ions (La3+ and Gd3+) to prepare Na9[EuxLa1‐xW10O36](EuxLa1‐xW10) and Na9[EuxGd1‐xW10O36](EuxGd1‐xW10) probe molecules. The doping of non‐fluorescent rare earth metal...