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The electronic structures and vertical excitation energies of square-planar complexes of Pt(II) and Pd(II) with glyoxilic acid oxime (H 2 GAO) (cis-K[Pt/Pd(GAO)(HGAO)]) were investigated in gas phase, aqueous solution and solid state by combination of DFT/TD-DFT methods, experimental UV–vis measurement in solution and diffuse UV–vis study in solid state. The solid-state chain structures were...
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