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The anion [3,3′‐Co(C2B9H11)2]− ([COSAN]−) produces aggregates in water. These aggregates are interpreted to be the result of CH⋅⋅⋅HB interactions. It is possible to generate aggregates even after the incorporation of additional functional groups into the [COSAN]− units. The approach is to join two [COSAN]− anions by a linker that can adapt itself to act as a crown ether. The linker has been chosen...
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