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Cobalamins are ubiquitous cobalt-based corrinoid cofactors of various transferases, exemplified by methyltransferases and adenosyltransferases. The cobalt oxidation state in these cobalamins directly influences their coordination environment and the redox properties. Cobalt ion in these cobalamins prominently exist in three oxidation states (I, II and III). The main focus of this review is the lowest...
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