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Simultaneous IR spectroscopic and catalytic measurements have been performed in order to investigate the nature of adsorbed species involved in the formation of N2O on Rh/Al2O3 in the course of the CO+NO reaction. Only nitrosyl species have been isolated that could be involved in the formation of N2 and N2O in accordance with previous kinetic investigations [Granger et al. J. Catal. 175 (1998) 194]...
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