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The conformational equilibria and IR isomerisation processes of glycolaldehyde (HOCH2CHO) conformers have been studied at low temperature in nitrogen cryogenic matrix. The effects of selective IR irradiation, in the νOH and νCH domains, have been followed by FTIR spectroscopy. After deposition the main form is the most stable one, CC (Cis-Cis), which features an intramolecular hydrogen bond. Upon...
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