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By means of topotactic low temperature reactions in a narrow temperature window, trivalent manganese in the LaMnO 3 perovskite is partly reduced to divalent, i.e., LaMnO 3-δ . Presently, phase relations, crystal structure and magnetic properties are described for metastable samples with nominal composition LaMnO 3-δ (0.00=<δ<0.25). A Jahn-Teller deformed...
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