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Reactions of laser-ablated scandium atoms with methane and methyl halides have been done during condensation in excess argon, and matrix infrared spectra were recorded for the products. Scandium is as effective as titanium in producing insertion products (CH 3 –ScX, X=H, F, Cl, Br) and higher oxidation-state methylidene complexes (CH 2 –ScHX) following α-hydrogen migration. However,...
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