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Water soluble phosphine ligand triphenylphosphine-3,3′,3″-trisulfonic acid trisodium salt (TPPTS) was used as the stabilizer as well as the activator to the palladium nanoparticles, which showed a high catalytic performance for aqueous phase Suzuki-Miyaura coupling reaction at room temperature.
A novel optically active 6,6'-didodecyl-1,1'-binaphthyl-metallophthalocyanine linked through crown ether units ((S)-Pc) has been synthesized. A stable monolayer of (S)-Pc that is able to bind metal ions can be formed at the air-water interface. Nonlinear absorption and optical limiting behavior of (S)-Pc have also been observed.
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