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We show here that optically active cryptophane 1 bearing phenol functions can efficiently bind the two enantiomers of 2‐(chloromethyl)oxirane, ethyloxirane, and 2,2′‐bioxirane derivatives in aqueous solution. The binding process is characterized by high‐field 1H NMR signals that are specific to the encapsulated species. In all cases, an enantioselective effect was observed and a relationship between...
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