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Donor–π–acceptor (D–π–A) molecules play an important role in various fields including polymer solar cells (PSCs) and dye‐sensitized solar cells (DSSCs). In PSCs, naphtho[1,2‐c:5,6‐c′]bis[1,2,5]thiadiazole (NTz) has emerged as a promising acceptor owing to its higher electron‐accepting ability compared with 2,1,3‐benzothiadiazole (BT), which is a widely used acceptor unit in DSSCs as well as PSCs....
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