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The ground state rotational spectrum of the near-spherical top molecule S 18 O 2 F 2 (sulfuryl fluoride) has been measured from 50 to 700GHz. As for the parent isotopologue, S 16 O 2 F 2 [K. Sarka, J. Demaison, L. Margulès, I. Merke, N. Heineking, H. Bürger, H. Ruland, J. Mol. Spectrosc. 200 (2000) 55–64], it was necessary to use a non-reduced Hamiltonian...
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