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Phosphonic acid (PA) self-assembled monolayers (SAMs) are utilized at critical interfaces between transparent conductive oxides (TCO) and organic active layers in organic photovoltaic devices (OPVs). The effects of PA deposition method and time on the formation of close-packed, high-quality monolayers is investigated here for SAMs fabricated by solution deposition, micro-contact printing, and spray...
Self-assembly of sub-100nm spherical silica nanoparticles into ordered, tightly packed three- and two-dimensional arrays was studied. Self-assembly by vertical evaporation was investigated for particles made by two methods: an optimized Stöber method recently reported from this laboratory and a modified reverse micelle method. Ordered, close-packed, two- and three-dimensional structures were formed...
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