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This study investigates effects of the electrolyte, of acidic and basic compounds, and of pH on the rotational and conformational order of octadecylsilane stationary phases with surface coverages of 3.09 and 6.45 μmol/m2. Both phases exhibit an increase in alkyl chain rotational and conformational order in 5–200 mM aqueous electrolyte solutions relative to water. These stationary phases are effectively...
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