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The dissociation of energy-selected acetic acid ions (CH 3 COOH + ) has been investigated by Threshold Photoelectron–photoion Coincidence (TPEPICO) spectroscopy. The lowest energy dissociation pathway for CH 3 COOH + is OH loss, and the 0K onset (E 0 ) of this process is measured to be 11.641±0.008eV. The reaction rate for this step is instantaneous on the time-scale...
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