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Fluctuating molecules of acetate ions in the (2x1)-acetate overlayer on TiO 2 (110)-(1x1) was observed by noncontact atomic force microscopy. Each acetate ion adsorbed on its stable site was observed as bright round protrusion ordered in a (2x1) periodicity. On the other hand, acetate ions at a boundary between domains with different phases along the [001] direction moved along the [001] direction...
The diffusion kinetics of adsorbed formate ions have been observed on a TiO2 (110) surface by scanning tunneling microscopy (STM) operated under ultrahigh vacuum. Formate ions in a desired area are removed without damage to the substrate, by rastering the monolayer with a high-biased STM tip. A patch of uncovered substrate is thus created in a (2 × 1)-formate monolayer. Time-resolved STM observation...
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