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A triamine, 2,2′,4,4′-tetrabromo-3″,4″-dimethyl-5,5′-bis(di(4-methylphenyl)amino)triphenylamine, was designed and synthesized as a model precursor for purely organic cationic high-spin systems. Cyclic voltammetry measurements revealed that the triamine gives stable mono-, di-, and tricationic states at ambient temperature. Novel electron transfer stopped-flow (ETSF) methods were invoked for characterizing...
A polyalkylated triamine, 2,2′,4,4′-tetrabromo-4″-methyl-5,5′-bis(di(3,4-di-methylphenyl)amino)triphenylamine, was designed and successfully synthesized as a model precursor for purely organic cationic high-spin systems. Cyclic voltammetry measurement revealed that the triamine gives stable mono- and dicationic states and fairly unstable tricationic state. Novel electron transfer stopped-flow (ETSF)...
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