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Quantum chemistry calculations at the MP2 and MRCI levels have been used to compute the energies of the stationary points and the minimum energy pathways (MEPs) between them for the dissociation and isomerization reactions of the methylene amido-gene radical. The MEPs for H 2 CN→trans-HCNH→cis-HCNH, H 2 CN→H+HCN, cis-HCNH→H+{HCN, HNC}, trans-HCNH→H+{HCN, HNC} and collinear CN+H ...
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