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An extended MM3 model has been used to identify all low energy configurations for U(IV) complexes with catecholate and aquo ligands. Both stochastic and systematic conformational analyses of [U(cat) n (OH 2 ) 8-2n ] 4-2n complexes, n=1-4, establish that 20 of the 67 possible stereochemistries are minima on the MM3 potential surface. The...
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