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Alle für einen: Phosphan‐ligierte Platin(II)‐Elektrophile können Polyalkane zur Teilnahme an Cyclisierungskaskaden aktivieren, ohne dass spezielle terminierende Gruppen benötigt werden (siehe Schema). Wie im Fall der natürlichen Cyclase‐Enzyme sind terminale Alkene, die tertiäre Kationen bilden, gute Substrate, allerdings hängen die Feinheiten des Kettenabbruchs von der Anordnung der Doppelbindungen...
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