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We report a halogen–lithium exchange performed in the presence of various metal salts (ZnCl2, MgCl2⋅LiCl) on a broad range of sensitive bromo‐ or iodo(hetero)arenes using BuLi or PhLi as the exchange reagent and a commercially available continuous‐flow setup. The resulting diarylmagnesium or diarylzinc species were trapped with various electrophiles, resulting in the formation of polyfunctional (hetero)arenes...
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