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The solvolysis rates of X‐substituted benzhydryltetrahydrothiophenium ions (1) in pure and aqueous alcohols were determined at 25 °C and compared with the rates of the corresponding benzhydryldimethylsulfonium ions (2). The linear free energy relationship equation log k = sf(Ef + Nf) has been used to relate quantitatively the leaving group abilities of tetrahydrothiophene (THT) and dimethyl sulfide...
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