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A series of Cu‐pyrrolidone/spherical activated carbon (SAC) catalysts were prepared via a simple incipient wetness impregnation method and then assessed in acetylene hydrochlorination, and the catalytic evaluation result indicated that the 1‐methyl‐2‐pyrrolidinone (NMP) ligand was found to be the most effective one to significantly improve the activity and stability of Cu catalyst. The catalyst with...
Metal clusters were considered as excellent catalysts for methanol dissociation. In this work, two main decomposition mechanisms of methanol on Pt7, Pt3Cu4, and Cu7 clusters were investigated by the density functional theory. One was methanol direct dehydrogenation, and the other was non‐CO‐involved oxidation. Stable adsorption configurations, elementary reaction barriers, the potential energy surface...
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