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Highly diastereoselective aldol reactions in water using a catalytic amount of diarylborinic acid have been developed. The reactions proceeded smoothly in the presence of a small amount of an anionic surfactant and a Brønsted acid. Water was the most suitable solvent, and organic solvents such as ether and dichloromethane were ineffective in this system. Use of bis(4-trifluoromethylphenyl)borinic...
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