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D5h‐symmetric fullerene C70 (D5h‐C70) is one of the most abundant members of the fullerene family. One longstanding mystery in the field of fullerene chemistry is whether D5h‐C70 is capable of accommodating a rare‐earth metal atom to form an endohedral metallofullerene M@D5h‐C70, which would be expected to show novel electronic properties. The molecular structure of La@C70 remains unresolved since...
Auf direktem Weg: Heterofullerene mit eingebautem Bor sind nur wenig erforscht, da keine Bildungsroute ausgehend von C60 bekannt ist. Nun wurde gefunden, dass C59B−, eine elektronisch geschlossenschalige Spezies, durch einfache Atomaustauschreaktionen aus unbehandeltem C60 in der Gasphase gebildet wird.
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