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Eine neue Strategie zur nichtchromatographischen Extraktion von Metallofullerenen aus Lösungen von Lichtbogenruß wird von K. Itami, H. Shinohara et al. in ihrer Zuschrift auf S. 3166 ff. beschrieben. Diese Methode beruht auf der größenselektiven Komplexierung mit kommerziell erhältlichem Cycloparaphenylen (CPP). Beispielsweise kann Gd@C82 durch die Addition von [11]CPP selektiv aus einer Fullerenmischung...
A new strategy for the non‐chromatographic extraction of metallofullerenes from solutions of arc‐processed raw soot is based on the size‐selective complexation with cycloparaphenylene (CPP). [11]CPP has a high affinity for Mx@C82 (x=1, 2); for example, Gd@C82 can be selectively extracted from a fullerene mixture by the addition of [11]CPP. This approach should open new opportunities in metallofullerene...
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