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Cu2O is an ideal p‐type material for photo‐electrochemical (PEC) hydrogen evolution, although serious electron–hole recombination and photocorrosion restrict its further improvement for PEC activity. In this work, CeO2 nanoparticles (NPs) self‐assemble on the surface of Cu2O octahedra, thus successfully forming a Cu2O/CeO2 structure in which p–n heterojunctions and micro‐mesocrystals (m‐MCs) work...
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