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At present, the reactivity of cyclic alkanes is estimated by comparison with acyclic hydrocarbons. Due to the difference in the structure of cycloalkanes and acycloalkanes, the thermodynamic data obtained by analogy are not applicable. In this study, a molecular beam sampling vacuum ultraviolet photoionization time‐of‐flight mass spectrometer (MB‐VUV‐PI‐TOFMS) was applied to study the low‐temperature...
Highly oxygenated intermediates play an important role in the low‐temperature oxidation of fuels. In this study, a molecular beam sampling vacuum ultraviolet photoionization time‐of‐flight mass spectrometer (MB‐VUV‐PI‐TOFMS) is used to observe the low‐temperature oxidation products, especially highly oxygenated intermediates like ketohydroperoxide (KHP), keto‐dihydroperoxide (KDHP), olefinic hydroperoxides...
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