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For some gas-phase X−+CH3Y→XCH3+Y− SN2 nucleophilic substitution reactions a pre-reaction complex is formed in which the attacking anion binds to a H-atom to form X−⋯HCH2Y. In this work properties of this complex are investigated, for the OH−+CH3I and F−+CH3I reactions, to determine whether the HO−⋯HCH2I and F−⋯HCH2I complexes should be considered hydrogen-bonded complexes. Properties considered for...
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