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In der überfüllten Zellumgebung wurden Mn‐basierte SOD‐Mimetika mit einem analogen [13C6LCoII] (L=Ligand) als Standard in komplexen Zelllysaten mittels Ionenmobilitätsspektrometrie gekoppelt an Massenspektrometrie (IMS‐MS) nachgewiesen und quantifiziert. Clotilde Policar et al. zeigen in ihrem Forschungsartikel (e202203066), dass IMS leistungsfähig genug ist, um Komplexe des gleichen Liganden mit...
The detection and quantification of exogenous metal complexes are crucial to understanding their activity in intricate biological media. MnII complexes are difficult to detect and quantify because of low association constants, and high lability. The superoxide dismutase (SOD) mimic (or mimetic) labelled Mn1 is based on a 1,2‐di‐aminoethane functionalized with imidazole and phenolate and has good intrinsic...
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