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The new bis(phosphino)amido ligand, [MePNP Ph ], that incorporates (i) an ortho-tolylene linker between nitrogen and phosphorus and (ii) phenyl substituents on phosphorus, has been synthesized as its protonated derivative, [MePNP Ph ]H, via sequential treatment of (2-Br,4-Me-C 6 H 3 ) 2 NH with (i) Bu n Li, (ii) Ph 2 PCl and (iii) HCl. Deprotonation...
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