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All‐solid‐state sodium (Na) batteries (ASSSBs) using sulfide‐based solid electrolytes (SEs) have attracted intensive attention due to their superior safety, high energy density, and low cost. However, the interfacial issue is one of the biggest challenges to achieve high‐performance sulfide‐based ASSSBs due to the serious reactions between active Na metal and sulfide SEs at the interface. To address...
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