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Tris(triazolyl)borate (Ttz) is a proton responsive ligand, and the redox potential of Ttz complexes can be altered by protonation. Protonation events can therefore alter the thermodynamics of reduction of copper complexes, and this is relevant to nitrite reduction mediated by copper complexes wherein Cu(II) reduction to Cu(I) is the first step. The electrochemical behavior of tris(triazolyl)borate...
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