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Direct complexation of (amino)(phosphino)carbene 1a and (amino)(oxy)carbene 1b featuring a phosphino group in position-6 to the carbene with [Rh(CO) 2 Cl] 2 has been studied. With the 1,2-bidentate ligand 1a, an original cationic complex 2 featuring two (amino)(phosphino)carbenes η 2 -bonded to the metal has been isolated in 79% yield. In the case of the 1,6-bidentate ligand...
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