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The first example of homogeneous copper‐catalyzed aerobic oxidation of aldehydes is reported. This method utilizes atmospheric oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification.
Nur wenig Abfall: Arylether sind über eine oxidative Kondensation von Alkoholen mit 2‐Cyclohexenonen zugänglich. Die Reaktion ergänzt die bestehenden Synthesemethoden und ermöglicht einen direkten Zugang zu einer Vielzahl an funktionalisierten Produkten. Darüber hinaus fällt durch die Verwendung von Sauerstoff als Oxidationsmittel lediglich Wasser als Nebenprodukt der katalytischen Reaktion an, und...
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