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Weißer Phosphor, gelbes Arsen und AsP3 werden durch einen Komplex mit Chrom‐Chrom‐Fünffachbindung in einem Schritt unter Bildung seltener, terminal gebundener cyclo‐P42−‐, cyclo‐As42−‐ und cyclo‐AsP3‐Einheiten aktiviert. Die anschließende Umsetzung mit einem Überschuss an [W(CO)5(thf)] führt zur Koordination eines [W(CO)5]‐Fragments in der laut DFT‐Rechnungen thermodynamisch stabilsten Form.
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