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Nanomaterials are rich in potential, particularly for the formation of scaffolds that mimic the landscape of the host environment of the cell. This niche arises from the spatial organization of a series of biochemical and biomechanical signals. Self‐assembling peptides have emerged as an important tool in the development of functional (bio‐)nanomaterials; these simple, easily synthesized subunits...
This review article covers recent developments in the use of enzyme‐catalyzed reactions to control molecular self‐assembly (SA), an area that merges the advantages of biocatalysis with soft materials self‐assembly. This approach is attractive because it combines biological (chemo‐, regio‐, and enantio‐) selectivity with the versatility of bottom up nanofabrication through dynamic SA. We define enzyme‐assisted...
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