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Despite many exploratory studies over the past several decades, the presently known transition metals that form homoleptic transition‐metal hydride complexes are limited to the Groups 7–12. Here we present evidence for the formation of Mg3CrH8, containing the first Group 6 hydride complex [CrH7]5−. Our theoretical calculations reveal that pentagonal‐bipyramidal H coordination allows the formation...
Über die Brücke: Mit zeitaufgelöster oberflächenverstärkter IR‐Spektroskopie (SEIRAS) in Kombination mit Chronoamperometrie wird nachgewiesen, dass Ameisensäure über brückenartig gebundenes adsorbiertes Formiat oxidiert wird und dass die Formiatzersetzung der geschwindigkeitsbestimmende Schritt ihrer Elektrooxidation an Pt zu CO2 ist. Der Beitrag der direkten Oxidation von Ameisensäure über schwach...
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